Here's how to do it (as of Aug 2020). After you have set up your business OnedriveOneDrive account on your machine by installing the OnedriveOneDrive desktop app, you can now "add an account" to your local machine, by following these steps:
- left-click the OneDrive icon in the system tray
- Left-click "More", then left-click "Settings" to open the onedriveOneDrive settings window.
- On the "Account" tab, left-click the "Add an account" button.
- You will be presented with a login for your personal account. Enter your credentials for you personal OnedriveOneDrive account here.
- After clicking next, confirm the path that you want OnedriveOneDrive to sync to on your local machine. Make sure this is different from your business OneDrive filepath.
Click through the remaining wizard steps, and you are done! In Windows Explorer, you should see 2 OnedriveOneDrive entries in the treeview. Hope this helps!